THE ENERGETIC STABILIZATION CAUSED BY A PLANAR-TETRACOORDINATE CARBON-ATOM - A DYNAMIC NMR SPECTROSCOPIC STUDY OF THE DIMETALLABICYCLE [(CP(2)ZR)(2)-(MU-C-EQUIVALENT-TO-CCH3)(MU-H3CCCCH3)]BPH(4)

被引：31

作者：

ERKER, G

ROTTGER, D

机构：

[1] Organisch-Chemisches Institut, Universität Münster, D-48149

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

About 12 kcalmol−1 lower in energy than the dimetallacyclopentene 2 is the isomer 1 with a planar‐tetracoordinate C atom. This value was determined when the automerization reaction of 1 was studied by dynamic NMR spectroscopy. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1623 / 1625

页数：3

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