CHEMICAL SPECIATION IN THE COPPER (I)-AMMONIA-CHLORIDE SYSTEM

被引：11

作者：

SOLIS, JS ^{[1
]}

HEFTER, G ^{[1
]}

MAY, PM ^{[1
]}

机构：

[1] MURDOCH UNIV,SCH MATH & PHYS SCI,MURDOCH,WA 6150,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 07期

关键词：

D O I：

10.1071/CH9951283

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical speciation in the system Cu-I/NH3/Cl- which may be represented by the general equilibrium pCu(I)(aq)+qNH(3)(aq)+rCl(-)(aq)reversible arrow Cu-p(NH3)(q)Cl-r((p-r)+)(aq) has been studied by glass electrode potentiometry at 25.0 degrees C and an ionic strength of 1.00 M (NaClO4). A number of binary and ternary complexes were detected with formation constants, beta(pqr): log beta(120) = 11.381+/-0.077, log beta(111) = 8.920+/-0.045, log beta(112) = 8.82+/-0.18 and log beta(121)=11.33+/-0.24. The ionization constant of water (pK(W)) and the protonation constant of ammonia (pK(a)) obtained by the same procedures were 13.7462+/-0.0012 and 9.4613+/-0.0010 at I = 1 (NaClO4), and 13.7165+/-0.0010 and 9.4521+/-0.0007 at I = 1 (NaCl) respectively

引用

页码：1283 / 1292

页数：10

共 42 条

[1] STABILITY OF METAL HALIDE COMPLEXES IN AQUEOUS SOLUTION .7. CHLORIDE COMPLEXES OF COPPER(I) [J].

AHRLAND, S ;

RAWSTHORNZ, J .

ACTA CHEMICA SCANDINAVICA, 1970, 24 (01) :157-+

[2] THERMODYNAMICS OF METAL-COMPLEX FORMATION IN AQUEOUS-SOLUTION .12. EQUILIBRIUM MEASUREMENTS ON COPPER(I) BROMIDE, IODIDE AND THIOCYANATE SYSTEMS [J].

AHRLAND, S ;

TAGESSON, B .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1977, 31 (08) :615-624

[3]

AHRLAND S, 1991, REV INORG CHEM, V11, P195

[4]

ANDREGG G, 1967, HELV CHIM ACTA, V50, P2333

[5]

[Anonymous], [No title captured]

[6] METAL AMMINE FORMATION IN SOLUTION .25. THE STABILITY CONSTANT OF THE TRIAMMINE COPPER(I) COMPLEX [J].

BJERRUM, J .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1986, 40 (03) :233-235

[7] SYNTHESIS, MOLECULAR-STRUCTURES, PROPERTIES AND REACTIONS OF HALO(AMINE)COPPER(I) AND CARBONYL(AMINE)COPPER(I) COMPLEXES [J].

CAULTON, KG ;

DAVIES, G ;

HOLT, EM .

POLYHEDRON, 1990, 9 (19) :2319-2351

[8]

Christensen JJ., 1983, HDB METAL LIGAND HEA

[9]

COURTURIER Y, 1973, B SOC CHIM FR, P439

[10]

FISCHER R, 1964, B SOC CHIM FR, P2920

← 1 2 3 4 5 →