SYNTHESIS AND CHARACTERIZATION OF OPTICALLY-ACTIVE, HOMOCHIRAL DENDRIMERS

被引：48

作者：

CHOW, HF

FOK, LF

MAK, CC

机构：

[1] Department of Chemistry, The Chinese University of Hong Kong, Shatin, N.T.

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)73234-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis and optical activity measurement of homochiral, monodisperse dendrimers is reported. Optically active (2R, 3R)-tartaric acid is used to construct the zero and first-generation optically active, homochiral dendrimers 1 and 2 in good yields. The relationship between the optical rotation of all these molecules and the number of chiral tartaric acid units resided in them is explored.

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页码：3547 / 3550

页数：4

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