SYNTHESIS AND SOME PROPERTIES OF POLYOXYHEXAKIS(DIMETHYLSILYLENE) AND ITS COPOLYMERS WITH DIMETHYLSILOXANE

被引：14

作者：

CHOJNOWSKI, J ^{[1
]}

FORTUNIAK, W ^{[1
]}

GLADKOVA, N ^{[1
]}

PLUTA, M ^{[1
]}

SCIBIOREK, M ^{[1
]}

ZAVIN, B ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INEOS,AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS | 1995年 / 5卷 / 01期

关键词：

POLYOXYHEXAKIS (DIMETHYLSILYLENE); DIMETHYLSILOXANE; COPOLYMER;

D O I：

10.1007/BF01157520

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of polyoxyhexakis(dimethylsilylene), 1, by the hydrolytic polycondensation of alpha,omega-dichlorohexakisdimethylsilylene, 2, and by cationic ring-opening polymerization of dodecamethyloxahexasilacycloheptane, D-6(1), initiated with a protic acid is reported. The possibility of synthesis of alternative copolymers composed of oxyhexakis(dimethylsilylene) units and dimelhylsiloxane or oligodimethylsiloxane units were also explored. Polymers are characterized by NMR spectroscopy. Their thermal behavior is discussed.

引用

页码：7 / 30

页数：24

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