COS TRAPPING BY PALLADIUM PYRAZOLATES - ADDITION VS CLATHRATION

被引：12

作者：

MASCIOCCHI, N ^{[1
]}

MORET, M ^{[1
]}

SIRONI, A ^{[1
]}

ARDIZZOIA, GA ^{[1
]}

CENINI, S ^{[1
]}

LAMONICA, G ^{[1
]}

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001955

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[{Pd(dmpz)(2)(Hdmpz)(2)}(2)] (Hdmpz = 3,5-dimethylpyrazole) reacts with COS, both in solution and in the solid state, affording [Pd{SC(O)dmpz}(2)] and [{Pd(dmpz)(2)(Hdmpz)(2)}2]. COS, respectively; the structure of the latter is determined by ab initio methods from conventional X-ray powder diffraction data only.

引用

页码：1955 / 1956

页数：2

共 11 条

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