SYNTHESIS OF 2 TYPES OF INTERCALATION COMPOUNDS OF K4NB6O17 WITH TRIS(2,2'-BIPYRIDYL) METAL-COMPLEX IONS

被引：59

作者：

NAKATO, T ^{[1
]}

SAKAMOTO, D ^{[1
]}

KURODA, K ^{[1
]}

KATO, C ^{[1
]}

机构：

[1] WASEDA UNIV, DEPT APPL CHEM, OHKUBO 3, SHINJUKU KU, TOKYO 169, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 02期

关键词：

D O I：

10.1246/bcsj.65.322

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

K4Nb6O17 is a layered material with two different types of interlayer spaces, interlayer I and interlayer II. It was found that two types of intercalation compounds of K4Nb6O17 with alkylammonium ions were formed, one in which alkylammonium ions were present in interlayer I only, and the other in which they were present in both the interlayers. Intercalation of [M(bpy)3]2+ (M: Fe, Ru, Ni) into K4Nb6O17 was carried out using these two types of alkylammonium-intercalated K4Nb6O17 as the intermediates. Ion exchange reactions of the interlayer alkylammonium ions for the complex ions were conducted, and the formation of two types of products, one in which [M(bpy)3]2+ ions were present in interlayer I only and the other in which they were present in both the interlayers, was confirmed from powder X-ray diffraction patterns and the compositions of the products.

引用

页码：322 / 328

页数：7

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