DIASTEREOSELECTIVE OXIDATION OF ARYLSULFIDES

被引：16

作者：

BOWER, JF ^{[1
]}

WILLIAMS, JMJ ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 38期

关键词：

D O I：

10.1016/0040-4039(94)88239-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Arylsulfides containing an enantiomerically pure oxazoline in the ortho-position have been oxidised to the corresponding sulfoxides with a variety of reagents. When the oxazoline unit contains a 4-hydroxymethyl group, good levels of diastereocontrol have been obtained using mCPBA (96:4) or t-butylhydroperoxide and titanium tetraisopropoxide (97:3) as the oxidant. This diastereocontrol provides an effective example of 1,6-asymmetric induction.

引用

页码：7111 / 7114

页数：4

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