ADDITIONS OF CYCLO-(AR2SI)(4) AND (AR2GE)(4) TO C-60

被引：17

作者：

KUSUKAWA, T ^{[1
]}

KABE, Y ^{[1
]}

ANDO, W ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 05期

关键词：

D O I：

10.1021/om00005a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photochemical reaction of cyclotetrasilane 1a with C-60 afforded stable 1:1 adducts 2a and 3a; the latter was obtained from a rearrangement of the cyclotetrasilane unit. Similarly, cyclotetragermane 1c gave 2c and the rearranged product 3c. In the case of cyclotetrasilane 1b, only the rearranged product 3b was obtained in high yield. The structures of all compounds were determined by spectroscopic methods, including Si-29-H-1 HMBC hetero nuclear shift correlation experiments.

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页码：2142 / 2144

页数：3

相关论文

共 23 条

[1] ORGANIC-CHEMICAL DERIVATION OF FULLERENES .4. ADDUCT OF C70 AT THE EQUATORIAL BELT - PHOTOCHEMICAL CYCLOADDITION WITH DISILIRANE [J].

AKASAKA, T ;

MITSUHIDA, E ;

ANDO, W ;

KOBAYASHI, K ;

NAGASE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) :2627-2628

[2] REACTION OF C60 WITH SILYLENE, THE 1ST-FULLERENE SILIRANE DERIVATIVE [J].

AKASAKA, T ;

ANDO, W ;

KOBAYASHI, K ;

NAGASE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (04) :1605-1606

[3] PHOTOCHEMICAL [2+3] CYCLOADDITION OF C-60 WITH DISILIRANES [J].

AKASAKA, T ;

ANDO, W ;

KOBAYASHI, K ;

NAGASE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) :10366-10367

[4] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY [J].

ALLEMAND, PM ;

KOCH, A ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1050-1051

[5] REDUCTIVE COUPLING REACTIONS OF DIHALOGENOGERMANES WITH MAGNESIUM AND MAGNESIUM BROMIDE - SIMPLE PREPARATION OF CYCLOTRIGERMANES AND CYCLOTETRAGERMANES [J].

ANDO, W ;

TSUMURAYA, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (20) :1514-1515

[6] PATTERNS FOR ADDITION TO C-60 [J].

DIXON, DA ;

MATSUZAWA, N ;

FUKUNAGA, T ;

TEBBE, FN .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (15) :6107-6110

[7] ELECTROCHEMICAL DETECTION OF FULLERONIUM AND HIGHLY REDUCED FULLERIDE (C-60(5-)) IONS IN SOLUTION [J].

DUBOIS, D ;

KADISH, KM ;

FLANAGAN, S ;

WILSON, LJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7773-7774

[8]

HAMMOND GS, 1992, ACS S SERIES, V481

[9] EFFICIENT PRODUCTION OF C60 (BUCKMINSTERFULLERENE), C60H36, AND THE SOLVATED BUCKIDE ION [J].

HAUFLER, RE ;

CONCEICAO, J ;

CHIBANTE, LPF ;

CHAI, Y ;

BYRNE, NE ;

FLANAGAN, S ;

HALEY, MM ;

OBRIEN, SC ;

PAN, C ;

XIAO, Z ;

BILLUPS, WE ;

CIUFOLINI, MA ;

HAUGE, RH ;

MARGRAVE, JL ;

WILSON, LJ ;

CURL, RF ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8634-8636

[10]

HIRSCH A, 1993, ANGEW CHEM INT EDIT, V32, P1138, DOI 10.1002/anie.199311381