SYNERGISM OF ZSM-22 AND Y-ZEOLITES IN THE BIFUNCTIONAL CONVERSION OF N-ALKANES

被引：83

作者：

PARTON, R

UYTTERHOEVEN, L

MARTENS, JA

JACOBS, PA

FROMENT, GF

机构：

[1] KATHOLIEKE UNIV LEUVEN, CTR OPPERVLAKTECHEM & KATALYSE, KARD MERCIERLAAN 92, B-3001 HEVERLEE, BELGIUM

[2] STATE UNIV GHENT, PETROCHEM TECH LAB, B-9000 GHENT, BELGIUM

来源：

APPLIED CATALYSIS | 1991年 / 76卷 / 01期

关键词：

BIFUNCTIONAL CATALYSIS; ISOMERIZATION; N-ALKANES; SYNERGISM; ZSM-22; ZSM-Y;

D O I：

10.1016/0166-9834(91)80009-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Intimate mixtures of bifunctional catalysts based on ZSM-22 and Y zeolites do not show merely the intermediate catalytic properties between those found for the individual zeolites. Such mixtures produce enhanced yields of multibranched isodecanes from n-decane. A mechanistic explanation for this synergetic effect is given. New experimental evidence is provided for the occurrence of free gas-phase olefinic intermediates in bifunctional catalysis with zeolites.

引用

页码：131 / 142

页数：12