NUCLEATION AND GROWTH OF CUBIC BN CRYSTALS IN THE PRESENCE OF CA3B2N4+XLIF AS FLUX-PRECURSOR

被引:15
作者
VEL, L
DEMAZEAU, G
机构
[1] Laboratoire de Chimie du Solide, CNRS, 33405 Talence Cedex
关键词
D O I
10.1016/0038-1098(91)90467-A
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Cubic boron nitride was prepared from hexagonal BN using as flux-precursor a mixture of calcium boronitride Ca3B2N4 and lithium fluoride LiF. The diagram of c-BN formation was determined for the composition: Ca3B2N4 + 1 LiF. The effects of the temperature on the conversion yields and the morphology of c-BN crystals were studied at constant pressure. The influence of the BN crystallinity on the solubilization in the fluoronitride flux was pointed out using disordered forms of BN.
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页码:1 / 4
页数:4
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