DICOPPER(I) COMPLEXES OF THE NOVEL PHOSPHORUSBIPYRIDYL LIGAND 6-DIPHENYLPHOSPHINO-2,2'-BIPYRIDYL

被引：19

作者：

FIELD, JS ^{[1
]}

HAINES, RJ ^{[1
]}

PARRY, CJ ^{[1
]}

SOOKRAJ, SH ^{[1
]}

机构：

[1] UNIV NATAL,DEPT CHEM,POB 375,PIETERMARITZBURG 3200,SOUTH AFRICA

来源：

POLYHEDRON | 1993年 / 12卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83064-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 6-diphenylphosphino-2,2'-bipyridine (Ph2Pbipy) with copper(I) precursors such as [Cu(MeCN)4]+ and [Cu(2,2'-bipy)(MeCN)2]+ affords dinuclear phosphorusbipyridyl ligand-bridged dicopper products and in particular [Cu2(mu-Ph2Pbipy)2 (MeCN)2]2+ (1) and [Cu2(2,2'-bipy)(mu-Ph2Pbipy)2]2+ (2), respectively. The ligand coordinates head-to-tail in 1, and head-to-head in 2, as established by single crystal X-ray diffraction studies.

引用

页码：2425 / 2428

页数：4

共 13 条

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