AZACRYPT AND HOST FOR LEAD - NMR AND STRUCTURAL STUDIES

被引:26
作者
MARTIN, N [1 ]
MCKEE, V [1 ]
NELSON, J [1 ]
机构
[1] QUEENS UNIV BELFAST,DEPT CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND
关键词
CRYSTAL STRUCTURES; NMR STUDY; LEAD COMPLEXES; AMINE CRYPTAND COMPLEXES; AZACRYPTAND COMPLEXES;
D O I
10.1016/0020-1693(94)03812-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A near spherical octaamine cryptand forms a thermodynamically and kinetically stable lead complex, suggesting a role as a potential scavenger of this cation; X-ray crystallographic structure determination reveals an irregular site for the Pb2+ cation, with four short and four long Pb-N contacts.
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页码:5 / 8
页数:4
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