DIRECT ANALYSIS OF HYDROGEN-TRANSFER REACTION FROM P-BENZOSEMIQUINONE RADICAL TO P-BENZOQUINONE BY TIME-RESOLVED CIDNP METHOD

被引：1

作者：

AIZAWA, T

ARAKI, Y

SHINDO, K

MAEDA, K

AZUMI, T

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1994年 / 50卷 / 8-9期

关键词：

D O I：

10.1016/0584-8539(94)80077-4

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The rate constant of the hydrogen transfer reaction from p-benzosemiquinone radical to p-benzoquinone was measured by the time-resolved CIDNP technique. The time dependence of the CIDNP intensity of the products, p-benzoquinone and p-hydrobenzoquinone, can be simulated by kinetic treatment. From the simulation, the rate constant of the hydrogen transfer is obtained.

引用

页码：1443 / 1450

页数：8

共 15 条

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