FIRST AMIDO-FUNCTIONALIZED ANSA-MOLYBDENOCENE-TYPE COMPLEXES

被引：16

作者：

HERRMANN, WA

BARATTA, W

MORAWIETZ, MJA

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, D-85747 Garching

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 497卷 / 1-2期

关键词：

MOLYBDENUM; AMINO FUNCTIONALIZED CYCLOPENTADIENYL; AMIDE;

D O I：

10.1016/0022-328X(95)05504-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

First examples of tetravalent molybdenocene-type compounds containing N-functionalized pi-aromatic ligands are described. Thus, the ''metal amide route'' starting from Mo[N(CH3)(2)](4) was used to synthesize [Si(CH3)(2)(C5H4)(NC6H5)]Mo[N(CH3)(2)](2) from the ligand Si(CH3)(2)(C5H5)(NHC6H5) in 60% yield. Related Mo(IV) complexes are reported. It appears that the Mo(IV) amides are least susceptible to redox side reactions.

引用

页码：C4 / C6

页数：3

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