REGIOSELECTIVITY OF PHOTOCHEMICAL ANNULATIONS OF CHROMIUM CARBENE COMPLEXES

被引：27

作者：

MERLIC, CA

ROBERTS, WM

机构：

[1] Department of Chemistry, Biochemistry University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)60130-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regioselectivity of photochemical benzannulation reactions of chromium biarylcarbene complexes is reported. Excellent selectivity is observed in furyl- and naphthyl-substituted substrates. Interesting ortho verses para selectivity is found in meta substituted (biphenyl)carbene substrates.

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页码：7379 / 7382

页数：4

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