PHOTOELECTROCHEMICAL PROPERTIES ORF SULFIDIZED TIO2 ELECTRODES

被引：8

作者：

GUO, RJ ^{[1
]}

WANG, MH ^{[1
]}

TSO, TL ^{[1
]}

PERNG, TP ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 300,TAIWAN

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 1995年 / 20卷 / 07期

关键词：

D O I：

10.1016/0360-3199(94)E0047-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pure and Nb-doped TiO2 (with 0.05mol% Nb2O5) pellets were reacted with sulfur at 900 or 1000-degrees-C. The effect of substitution of sulfur for oxygen on the photoelectrochemical (PEC) properties were studied. The phases and microstructures before and after sulfidation were examined. For pure TiO2 sulfidation greatly improved the PEC performance. Reaction at a higher temperature for a longer time allowed more sulfidation and resulted in a higher PEC current. For Nb-doped TiO2, high-temperature sulfidation also induced segregation of Nb on the grain boundaries. The PEC properties of the sulfidized electrodes could be correlated with the extent of sulfidation and the change of microstructures.

引用

页码：561 / 566

页数：6

共 14 条

[1] PHOTOELECTROCHEMICAL SOLAR-CELLS BASED ON TIS2/TIO2(TIOXSY) PHOTOELECTRODES
BABU, KSC
SRIVASTAVA, ON
[J]. CRYSTAL RESEARCH AND TECHNOLOGY, 1988, 23 (04) : 555 - 560
[2] INFLUENCE OF COPPER ADDITION ON OPTICAL-PROPERTIES OF TIO2
BLONDEAU, G
FROELICHER, M
FROMENT, M
GOFF, AHL
ZERBINO, J
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (09) : 1592 - 1596
[3] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
FUJISHIMA, A
HONDA, K
[J]. NATURE, 1972, 238 (5358) : 37 - +
[4] THE PHOTOELECTROCHEMICAL PROPERTIES OF NB-DOPED TIO2 SEMICONDUCTING CERAMIC MEMBRANE
KIKKAWA, H
OREGAN, B
ANDERSON, MA
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 309 (1-2): : 91 - 101
[5] CHARACTERISTICS OF THE SURFACE-STATES PRODUCED ON TITANATE PHOTOANODES BY MECHANICAL POLISHING
KUTTY, TRN
DEVI, LG
AVUDAITHAI, M
[J]. SOLAR ENERGY MATERIALS, 1990, 20 (04): : 307 - 321
[6] SACRIFICIAL WATER PHOTOCLEAVAGE USING NB-DOPED TIO2 FINE PARTICLES UNDER BAND-GAP IRRADIATION
KUTTY, TRN
AVUDAITHAI, M
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1990, 15 (09) : 621 - 628
[7] SEMICONDUCTOR ELECTRODES .7. DIGITAL-SIMULATION OF CHARGE INJECTION AND ESTABLISHMENT OF SPACE-CHARGE REGION IN ABSENCE AND PRESENCE OF SURFACE-STATES
LASER, D
BARD, AJ
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (12) : 1828 - 1832
[8] LASER D, 1979, J ELECTROCHEM SOC, V126, P1011
[9] TRANSITION-METAL DOPANTS FOR EXTENDING THE RESPONSE OF TITANATE PHOTOELECTROLYSIS ANODES
MARUSKA, HP
GHOSH, AK
[J]. SOLAR ENERGY MATERIALS, 1979, 1 (3-4): : 237 - 247
[10] PHOTOELECTROCHEMICAL PROPERTIES OF POLYCRYSTALLINE TIO2 DOPED WITH 3D TRANSITION-METALS
MATSUMOTO, Y
KURIMOTO, J
SHIMIZU, T
SATO, E
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (05) : 1040 - 1044

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