A ONE-POT SYNTHESIS OF CONJUGATED FLUOROENYNES VIA 2,2-DIFLUOROVINYLCOPPER INTERMEDIATES

被引：17

作者：

ICHIKAWA, J

IKEURA, C

MINAMI, T

机构：

[1] Department of Applied Chemistry, Kyushu Institute of Technology, Kitakyushu, 804, Sensui-cho, Tobata

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 63卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)80572-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1-Difluoro-1,3-enynes have been synthesized in good yield via the in-situ generation of 1-alkyl-2,2-difluorovinylboranes by successive treatment of 2,2,2-trifluoroethyl p-toluenesulfonate with butyl-lithium and trialkylboranes, followed by the coupling reaction with 1-halo-1-alkynes in the presence of cuprous iodide.

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页码：281 / 285

页数：5

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