An adequate supply of available Ca in the soil solution of the pegging zone during fruit development is required for production of high yields of high quality peanuts (Arachis hypogaea L.). On low Ca soils, application of gypsum during early bloom is recommended in order to ascertain adequate availability of Ca. Reaction of gypsum in soils under leaching conditions vary considerably and play an important role in fruit development and yield of peanuts. A laboratory study was conducted in leaching soil columns to investigate the effects of one gypsum amendment on leaching of Ca, K, Mg, and SO4 to a depth of 8 cm (fruiting zone of peanut). Six soils of varying physical and chemical properties representative of major peanut growing soils in Georgia were utilized. Following leaching with 15 cm water through gypsum-amended soil columns, 50% to 56% and 74% to 77% of applied Ca and SO4, respectively, were leached below 8 cm in the sandy-Carnegie, Dothan, Fuquay and Tifton soils. The respective values for the sandy clay loam-Greenville and Faceville soils were 28% to 36% and 58% to 69%. Lower initial Ca status and greater leaching of Ca from the applied gypsum in the sandy soils as compared to sandy clay loam soils suggest greater beneficial effects of supplemental gypsum application for peanut production in the former soils than in the latter soils. Leaching of K or Mg (as percentage of Mehlich 1 extractable K or Mg) in gypsum-amended treatment was considerably greater in sandy soils than that in the sandy clay loam soils. In view of the reported adverse effects of high concentrations of soil K and Mg in the fruiting zone on the yield and quality of peanuts, greater leaching of K and Mg from the fruiting zone in gypsum amended sandy soils enable them to maintain a favorable cation balance for the production of high yields of quality peanuts.