FREE-RADICAL CHEMISTRY .8. ELECTROCHEMICAL FLUORINATION OF PARTLY FLUORINATED ETHERS

被引：18

作者：

CHAMBERS, RD ^{[1
]}

FUSS, RW ^{[1
]}

JONES, M ^{[1
]}

SARTORI, P ^{[1
]}

SWALES, AP ^{[1
]}

HERKELMANN, R ^{[1
]}

机构：

[1] UNIV DUISBURG,DEPT INORGAN CHEM,W-4100 DUISBURG,GERMANY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 49卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)85035-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Free-radical additions of hexafluoropropene to cyclic ethers may be carried out to achieve mono- or di-adducts and mixtures of isomers of di-adducts are formed. These adducts may be fluorinated, using electrochemical fluorination, to give the corresponding perfluoro-ethers and, in some cases, with surprising efficiency. Adducts of acyclic ethers are less efficiently fluorinated. © 1990.

引用

页码：409 / 419

页数：11

共 8 条

[1] CHAMBERS RD, 1986, J FLUORINE CHEM, V32, P309
[2] FREE-RADICAL CHEMISTRY .4. STEREOELECTRONIC EFFECTS IN THE ADDITIONS OF CYCLIC ETHERS TO FLUORINATED ALKENES
CHAMBERS, RD
GRIEVSON, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (11): : 2215 - 2218
[3] FREE-RADICAL CHEMISTRY .3. SUBSTITUENT EFFECTS IN ADDITIONS OF ETHERS TO FLUORINATED ALKENES
CHAMBERS, RD
GRIEVSON, B
KELLY, NM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (11): : 2209 - 2213
[4] FREE-RADICAL CHEMISTRY .5. A NEW APPROACH TO THE SYNTHESIS OF PERFLUORINATED ETHERS
CHAMBERS, RD
GRIEVSON, B
DRAKESMITH, FG
POWELL, RL
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1985, 29 (03) : 323 - 339
[5] CHAMBERS RD, IN PRESS J FLUORINE
[6] THE ELECTROCHEMICAL PERFLUORINATION (ECPF) OF PROPANESULFONYL FLUORIDES .1. PREPARATION AND ECPF OF 1-PROPANESULFONYL FLUORIDE AND 1,3-PROPANEDISULFONYL DIFLUORIDE
HOLLITZER, E
SARTORI, P
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1987, 35 (02) : 329 - 341
[7] HERSTELLUNG VON PERFLUORALKANEN UND PERFLUORCYCLOALKANEN
SANDER, M
BLOCHL, W
[J]. CHEMIE INGENIEUR TECHNIK, 1965, 37 (01) : 7 - &
[8] SANDERS M, 1961, Patent No. 879057

← 1 →