SYNTHESIS OF AN N2S-CYCLODECANE MACROCYCLE AND ITS NICKEL(II) COMPLEX

被引：23

作者：

CHANDRASEKHAR, S ^{[1
]}

MCAULEY, A ^{[1
]}

机构：

[1] UNIV VICTORIA,DEPT CHEM,POB 3055,VICTORIA V8W 3P6,BC,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 20期

关键词：

D O I：

10.1039/dt9920002967

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand 1-thia-4,8-diazacyclodecane ([10]aneN2S, L1) and its nickel(II) complex have been synthesised and characterised. The complex [Ni([10]aneN2S)2]Br2 crystallised in the space group P2(1)/n (no. 14) with a = 11.41 9(3), b = 9.439(2), c = 10.288(3) angstrom and beta = 96.66(3)-degrees. Refinement converged with R = 0.0411 (R' = 0.0472) for 115 parameters using 1559 reflections with l > 3sigma(l). The metal-ion complex is nominally octahedral with mean Ni-N and Ni-S bond lengths of 2.142(5) and 2.395(1) angstrom respectively. Oxidation of the nickel(II) complex results in the formation of a nickel(III) species which exhibits a tetragonally elongated geometry according to the ESR spectrum obtained. Spectroscopic and redox properties of the complex are compared with those of other ligands in the ten-membered series and with the nine-membered ring analogues.

引用

页码：2967 / 2970

页数：4

共 34 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2] TRANSITION-METAL COMPLEXES OF HOMOLEPTIC POLYTHIA CROWNS [J].

BELL, MN ;

BLAKE, AJ ;

GOULD, RO ;

HOLDER, AJ ;

HYDE, TI ;

LAVERY, AJ ;

REID, G ;

SCHRODER, M .

JOURNAL OF INCLUSION PHENOMENA, 1987, 5 (02) :169-172

[3] SYNTHESIS AND PROPERTIES OF THE RU(1,4,7-TRIAZACYCLONONANE)2(3+)/2+ COUPLE AND NMR-STUDY OF THE ELECTRON SELF-EXCHANGE [J].

BERNHARD, P ;

SARGESON, AM .

INORGANIC CHEMISTRY, 1988, 27 (15) :2582-2587

[4] COMPLEXES OF TRIDENTATE AND PENTADENTATE MACROCYCLIC LIGANDS [J].

BHULA, R ;

OSVATH, P ;

WEATHERBURN, DC .

COORDINATION CHEMISTRY REVIEWS, 1988, 91 :89-213

[5] STRUCTURAL AND ELECTROCHEMICAL STUDIES ON TRITHIA MACROCYCLIC COMPLEXES OF PALLADIUM [J].

BLAKE, AJ ;

HOLDER, AJ ;

HYDE, TI ;

ROBERTS, YV ;

LAVERY, AJ ;

SCHRODER, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 323 (02) :261-270

[6] CRYSTALLOGRAPHIC STUDY OF THE LOW-SPIN IRON(II) AND IRON(III) BIS COMPLEXES OF 1,4,7-TRIAZACYCLONONANE [J].

BOEYENS, JCA ;

FORBES, AGS ;

HANCOCK, RD ;

WIEGHARDT, K .

INORGANIC CHEMISTRY, 1985, 24 (19) :2926-2931

[7] NICKEL IN METALLOPROTEINS [J].

CAMMACK, R .

ADVANCES IN INORGANIC CHEMISTRY, 1988, 32 :297-333

[8] SYNTHESES, STRUCTURE, AND REACTIVITY OF COBALT AND NICKEL-COMPLEXES OF 1,4,7-TRITHIACYCLODECANE - SELF-EXCHANGE RATES FOR CO(S6)2+/3+ COUPLES FROM CO-59 NMR-SPECTROSCOPY [J].

CHANDRASEKHAR, S ;

MCAULEY, A .

INORGANIC CHEMISTRY, 1992, 31 (03) :480-487

[9] EVIDENCE FOR LIGAND ISOMERISM IN THE PALLADIUM(II) COMPLEX OF 1,4,7-TRITHIACYCLODECANE [J].

CHANDRASEKHAR, S ;

MCAULEY, A .

INORGANIC CHEMISTRY, 1992, 31 (12) :2663-2665

[10] SYNTHESES AND REACTIVITY OF NICKEL-COMPLEXES OF 8-AZA-1,5-DITHIACYCLODECANE AND THE MACROBICYCLIC LIGAND 1,2-BIS(8-AZA-1,5-DITHIA-8-CYCLODECANYL)ETHANE [J].

CHANDRASEKHAR, S ;

MCAULEY, A .

INORGANIC CHEMISTRY, 1992, 31 (11) :2234-2240

← 1 2 3 4 →