MULTICOMPONENT DETERMINATION OF CHLORINATED HYDROCARBONS USING A REACTION-BASED CHEMICAL SENSOR .3. MEDIUM-RANK 2ND-ORDER CALIBRATION WITH RESTRICTED TUCKER MODELS

被引：79

作者：

SMILDE, AK

TAULER, R

HENSHAW, JM

BURGESS, LW

KOWALSKI, BR

机构：

[1] UNIV WASHINGTON,CTR PROC ANALYT CHEM,SEATTLE,WA 98195

[2] UNIV WASHINGTON,CTR PROC ANALYT CHEM,SEATTLE,WA 98195

来源：

ANALYTICAL CHEMISTRY | 1994年 / 66卷 / 20期

关键词：

D O I：

10.1021/ac00092a010

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The calibration of a chemical sensor for chlorinated hydrocarbon analytes based on the Fujiwara reaction is described. This sensor generates a particular type of data: medium-rank second-order data. With this type of data it is possible to calibrate the sensor in such a way that quantitation for the analytes in the presence of unknown interferents is possible. The calibration method developed is a new approach based on so-called restricted Tucker models that utilize all available chemical information.

引用

页码：3345 / 3351

页数：7

共 16 条

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