A CATIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH(III) COMPLEX - SYNTHESIS AND STRUCTURE OF [BIPH(2)(HMPA)(2)][BF4] (HMPA=HEXAMETHYLPHOSPHORAMIDE)

被引：37

作者：

CARMALT, CJ

NORMAN, NC

ORPEN, AG

STRATFORD, SE

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,ENGLAND

[2] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)83156-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structure of the cationic, four-coordinate, ten-electron bismuth(III) complex [BiPh(2)(HMPA)(2)](+) (HMPA = hexamethylphosphoramide) is reported. The coordination geometry around the bismuth centre is that of a trigonal bipyramid with one equatorial site vacant and with phenyls in the other equatorial positions and the HMPA ligands in axial sites.

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页码：C22 / C24

页数：3

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