FEATURES OF LIVING RADICAL POLYMERIZATION OF VINYL MONOMERS IN HOMOGENEOUS SYSTEM USING N,N-DIETHYLDITHIOCARBAMATE DERIVATIVES AS PHOTOINIFERTERS

被引：152

作者：

OTSU, T ^{[1
]}

MATSUNAGA, T ^{[1
]}

DOI, T ^{[1
]}

MATSUMOTO, A ^{[1
]}

机构：

[1] OSAKA CITY UNIV,FAC ENGN,DEPT APPL CHEM,SUMIYOSHI KU,OSAKA 558,JAPAN

来源：

EUROPEAN POLYMER JOURNAL | 1995年 / 31卷 / 01期

关键词：

D O I：

10.1016/0014-3057(94)00122-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical polymerizations of styrene, methyl methacrylate, methyl acrylate, vinylacetate, acrylonitrile and methacrylonitrile were carried out in the presence of photoiniferters (RDC) bearing an N,N-diethyldithiocarbamate group. The effects of the structure of RDC on the polymerizations were investigated as well as the effects of the conditions such as the monomer and iniferter concentrations, the polymerizations temperature and the wavelength of the irradiation light. The appropriate conditions for the living radical polymerizations of these monomers were determined. Stabilization of the iniferter site at the chain end was also attempted.

引用

页码：67 / 78

页数：12

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