MODIFICATION OF NATURAL-RUBBER LATEX WITH PERACETIC-ACID

被引:180
作者
GELLING, IR
机构
[1] Malaysian Rubber Producers' Research, Assoc, Tun Abdul Razak Lab,, Hertford, Engl, Malaysian Rubber Producers' Research Assoc, Tun Abdul Razak Lab, Hertford, Engl
来源
RUBBER CHEMISTRY AND TECHNOLOGY | 1985年 / 58卷 / 01期
关键词
EPOXIDATION - PERACETIC ACID;
D O I
10.5254/1.3536060
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Sufficient peracetic acid was employed to achieve epoxidation levels from 25 to 100 mole% and the effect of concentration and reaction temperature on the structure and properties of the products investigated. Two distinct types of product were isolated: at high reagent concentrations and temperatures, epoxide ring-opened products predominated, whereas at low acid concentrations and moderate temperatures, epoxidized NR was isolated as the sole product, except in the case of 100 mole% reaction.
引用
收藏
页码:86 / 96
页数:11
相关论文
共 26 条
[1]  
[Anonymous], 2009, Press release, Patent No. 1083316
[2]  
BLOOMFIELD GF, 1934, J SOC CHEM IND LOND, V53, pT121
[3]  
COLCLOUGH T, 1962, T I RUBBER IND, V38, pT11
[4]  
DAVEY JE, UNPUB BRIT POLYM J
[5]   STRAIN CRYSTALLIZATION IN RANDOM CO-POLYMERS PRODUCED BY EPOXIDATION OF CIS 1,4-POLYISOPRENE [J].
DAVIES, CKL ;
WOLFE, SV ;
GELLING, IR ;
THOMAS, AG .
POLYMER, 1983, 24 (01) :107-113
[6]  
GELLING IR, UNPUB
[7]  
GELLING IR, 1979, P INT RUBBER C VENIC
[8]   C-13 NMR SPECTROSCOPIC STUDY OF EPOXIDIZED 1,4-POLYISOPRENE AND 1,4-POLYBUTADIENE [J].
GEMMER, RV ;
GOLUB, MA .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (11) :2985-2990
[9]  
GONSOVSKAYA TB, 1971, KAUCH REZINA, V30, P23
[10]  
GREENSPAN FP, 1964, CHEM REACTIONS POLYM