PREPARATION, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF ETA-1-N AND ETA-2-SE,SE' COMPLEXES OF A P2N4SE2 RING

被引：10

作者：

CHIVERS, T ^{[1
]}

DOXSEE, DD ^{[1
]}

HILTS, RW ^{[1
]}

MEETSMA, A ^{[1
]}

PARVEZ, M ^{[1
]}

VANDEGRAMPEL, JC ^{[1
]}

机构：

[1] UNIV GRONINGEN, DEPT POLYMER CHEM, 9747 AG GRONINGEN, NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1,5-Ph4P2N4Se2, 1, prepared by the treatment of Ph2PN2(SiMe3)3 with a mixture of SeCl4 and Se2Cl2 in acetonitrile, with [PtCl2(PEt3)]2 gives the adducts [PtCl2(PEt3)]n[eta1-N-Ph4P2N4Se2] (2, n = 1; 3, n = 2) in which the P2N4Se2 ring is shown by an X-ray structural determination of 3 to contain a transannular Se-Se interaction; the oxidative addition of 1 or 2 to Pt(C2H4)(PPh3)2 produces the corresponding eta2-Se,Se' complexes.

引用

页码：1330 / 1332

页数：3

共 17 条

[1]

ADEL J, 1988, CHIMIA, V42, P413

[2]

ADEL J, 1988, CHIMIA, V42, P70

[3]

[Anonymous], ATOMS POLYM ISOELECT

[4] THE PREPARATION, CHARACTERIZATION IN SOLUTION OF THE 7-PI RADICAL 1,2,4-TRISELENO-3,5-DIAZOLYLIUM AND THE 6-PI (1,2,4-TRISELENO-3,5-DIAZOLIUM)2+ CATIONS, AND THE X-RAY CRYSTAL-STRUCTURES OF (SENSENSE)2(ASF6)2 AND SENSENSE(ASF6)2 CONTAINING THE 1ST STABLE BINARY SELENIUM NITROGEN SPECIES [J].

AWERE, EG ;

PASSMORE, J ;

WHITE, PS ;

KLAPOTKE, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) :1415-1417

[5] DIE KRISTALLSTRUKTUR VON TETRASTICKSTOFFTETRASSLENID N4SE4 [J].

BARNIGHA.H ;

VONVOLKM.T .

ACTA CRYSTALLOGRAPHICA, 1966, 21 :571-&

[6] OXIDATIVE ADDITION OF HALOGENS TO 1,3-(PH2PN)2(SN)2 AND 1,5-(PH2PN)2(SN)2 - X-RAY CRYSTAL-STRUCTURE OF 1,5-(PH2PN)2(NSBR)2 AND A COMPARISON OF THE CRYSTAL-STRUCTURES OF THE 12-MEMBERED RING 1,3,7,9-(PH2PN)4(SN)2 AND THE CORRESPONDING DICATION (PH2PN)4(SN)2(2+) [J].

BURFORD, N ;

CHIVERS, T ;

RAO, MNS ;

RICHARDSON, JF .

INORGANIC CHEMISTRY, 1984, 23 (13) :1946-1952

[7]

CHERIN P, 1972, ACTA CRYSTALLOGR B, V28, P31

[8] LEWIS BASE PROPERTIES OF 1,5-DIPHOSPHADITHIATETRAZOCINES - CRYSTAL AND MOLECULAR-STRUCTURES OF 1,5-PH4P2N4S2ME+CF3SO3- [J].

CHIVERS, T ;

DENES, GY ;

LIBLONG, SW ;

RICHARDSON, JF .

INORGANIC CHEMISTRY, 1989, 28 (19) :3683-3688

[9] ETA-2-S,S'-1,5-DITHIA-2,4,6,8-TETRAZOCINE ANALOGS OF ETA-2-ALKENE COMPLEXES - PREPARATION AND ELECTRONIC-STRUCTURE OF PT[1,5-(ME2N)2C2N4S2](PPH3)2 [J].

CHIVERS, T ;

DHATHATHREYAN, KS ;

ZIEGLER, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (02) :86-88

[10] DIPHOSPHADISELENATETRAZOCINES - PREPARATION AND STRUCTURAL CHARACTERIZATION OF A PV2N4SE2 RING [J].

CHIVERS, T ;

DOXSEE, DD ;

FAIT, JF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (22) :1703-1705

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