HEXAAQUATITANIUM(III) TRIS(P-TOLUENESULFONATE) TRIHYDRATE

被引：22

作者：

AQUINO, MAS

CLEGG, W

LIU, QT

SYKES, AG

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194010826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [Ti(H2O)(6)](p-CH3C6H4SO3)(3).-3H(2)O consists of discrete cations, anions and solvate water molecules, all linked by a hydrogen-bonding network. Each Ti ion lies on an inversion centre and shows essentially octahedral coordination with Ti-O bonds in the range 2.018 (5)-2.046 (6) Angstrom.

引用

收藏

页码：560 / 562

页数：3

相关论文

共 11 条

[1] STRUCTURAL STUDIES ON THE CESIUM ALUMS, CSMIII[SO4]212H2O [J].

BEATTIE, JK ;

BEST, SP ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (10) :2105-2111

[2] SYNTHESES AND CRYSTAL AND MOLECULAR-STRUCTURES OF HEXAAQUARUTHENIUM(II) P-TOLUENESULFONATE AND HEXAAQUARUTHENIUM(III) P-TOLUENESULFONATE, [RU(H2O)6](C7H7SO3)2 AND [RU(H2O)6](C7H7SO3)3.3H2O [J].

BERNHARD, P ;

BURGI, HB ;

HAUSER, J ;

LEHMANN, H ;

LUDI, A .

INORGANIC CHEMISTRY, 1982, 21 (11) :3936-3941

[3] FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].

CLEGG, W .

ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28

[4] PRECISE STRUCTURAL CHARACTERIZATIONS OF THE HEXAAQUOVANADIUM(III) AND DIAQUOHYDROGEN IONS - X-RAY AND NEUTRON-DIFFRACTION STUDIES OF [V(H2O)6][H5O2](CF3SO3)4 [J].

COTTON, FA ;

FAIR, CK ;

LEWIS, GE ;

MOTT, GN ;

ROSS, FK ;

SCHULTZ, AJ ;

WILLIAMS, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (18) :5319-5323

[5]

COTTON FA, 1988, ADV INORG CHEM RAD, P1388

[6] CRYSTAL AND MOLECULAR-STRUCTURES OF HEXAAQUACOPPER(II) BENZENESULFONATE, TOLUENE-4-SULPHONATE AND D-CAMPHOR-10-SULPHONATE [J].

COULDWELL, C ;

PROUT, K ;

ROBEY, D ;

TAYLOR, R ;

ROSSOTTI, FJC .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAY) :1491-1499

[7] THE CRYSTAL STRUCTURE OF ZINC PARA-TOLUENE SULPHONATE HEXAHYDRATE [J].

HARGREAVES, A .

ACTA CRYSTALLOGRAPHICA, 1957, 10 (03) :191-195

[8]

SHELDRICK GM, 1993, SHELXL93 PROGR REF C

[9]

SHELDRICK GM, 1990, SHELXTL USER MANUAL

[10] REFINEMENT OF BETA-ALUM CSTI(SO4)2.12H2O [J].

SYGUSCH, J .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (MAR15) :662-665