HOMOGENEOUS CATALYTIC-HYDROGENATION OF OLEFINS USING RHH2(PH2N3)(PPH3)2 IN TETRAHYDROFURAN

被引：7

作者：

KAMEDA, N

IGARASHI, R

机构：

[1] Department of Chemistry, College of Science and Technology, Nihon University, Funabashi

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 75卷 / 01期

关键词：

D O I：

10.1016/0304-5102(92)80099-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic hydrogenation activity of RhH2(Ph2N3)(PPh3)2 in tetrahydrofuran with different unsaturated compounds (allyl alcohol, cinnamic alcohol, cinnamaldehyde, acrylic acid, acrolein, cinnamic acid, acrylonitrile, cinnamonitrile and styrene) has been studied. The results obtained with acrolein, acrylic acid and acrylonitrile showed reduction, although other substrates did not. The highest activity was observed with acrylonitrile. A possible mechanism for this reaction is suggested.

引用

收藏

页码：15 / 20

页数：6

相关论文

共 10 条

[1] ZEROVALENT PLATINUM CHEMISTRY .4. BISTRIPHENYLPHOSPHINEPLATINUM(O) COMPLEXES WITH SOME ACTIVATED MONO-OLEFINS AND MONOALKYNES [J].

CENINI, S ;

UGO, R ;

LAMONICA, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (03) :409-&

[2]

James B. R., 1979, ADV ORGANOMET CHEM, V17, P319

[3]

JAMES BR, 1973, HOMOGENEOUS HYDROGEN, P198

[4] FURTHER STUDIES ON HOMOGENEOUS HYDROGENATION OF OLEFINS USING TRIS(TRIPHENYLPHOSPHINE)HALOGENORHODIUM(I) CATALYSTS [J].

JARDINE, FH ;

OSBORN, JA ;

WILKINSO.G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (10) :1574-&

[5] TRIAZENE COMPLEXES OF GROUP VIII METALS [J].

KNOTH, WH .

INORGANIC CHEMISTRY, 1973, 12 (01) :38-44

[6] COMPLEXES OF PLATINUM METALS .4. 1,3-DIARYLTRIAZENIDO DERIVATIVES [J].

LAING, KR ;

ROBINSON, SD ;

UTTLEY, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (11) :1205-1214

[7] SELECTIVE HOMOGENEOUS HYDROGENATION OF ALK-1-ENES USING HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) AS CATALYST [J].

OCONNOR, C ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (11) :2665-+

[8] HIGHLY REACTIVE RH(I)HYDRIDO COMPOUNDS [J].

OKANO, T ;

YOSHIDA, T .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1983, 41 (04) :359-364

[9] PREPARATION AND PROPERTIES OF TRIS(TRIPHENYLPHOSPHINE)HALOGENORHODIUM(1) AND SOME REACTIONS THEREOF INCLUDING CATALYTIC HOMOGENEOUS HYDROGENATION OF OLEFINS AND ACETYLENES AND THEIR DERIVATIVES [J].

OSBORN, JA ;

JARDINE, FH ;

YOUNG, JF ;

WILKINSO.G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (12) :1711-&

[10] HOMOGENEOUS CATALYTIC-HYDROGENATION OF ALKENES BY ZERO-VALENT PALLADIUM COMPLEXES OF CIS-FIXED DINITROGEN LIGANDS [J].

VANASSELT, R ;

ELSEVIER, CJ .

JOURNAL OF MOLECULAR CATALYSIS, 1991, 65 (03) :L13-L19