REGIOSELECTIVE ORTHO SUBSTITUTION OF DIPHENYL SULFOXIDE CHROMIUM TRICARBONYL - COMPLEMENTARY STEREOSELECTIVITIES FOR THE MONO-ANIONS AND DI-ANIONS

被引：34

作者：

DAVIES, SG ^{[1
]}

LOVERIDGE, T ^{[1
]}

CLOUGH, JM ^{[1
]}

机构：

[1] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mono- and di-anions derived from diphenyl sulfoxide chromium tricarbonyl and lithium diisopropylamide show complementary stereoselectivities in their reactions with electrophiles (D+, Mel, Me(3)SiCl).

引用

页码：817 / 818

页数：2

共 23 条

[1] ENANTIOSELECTIVE ORTHO-LITHIATION OF AMINALS OF BENZALDEHYDE CHROMIUMTRICARBONYL COMPLEX [J].

ALEXAKIS, A ;

KANGER, T ;

MANGENEY, P ;

ROSEMUNCH, F ;

PERROTEY, A ;

ROSE, E .

TETRAHEDRON-ASYMMETRY, 1995, 6 (01) :47-50

[2] ASYMMETRIC DEPROTONATION AND COMPLEXATION REACTIONS MEDIATED BY CHIRAL KETALS AS A ROUTE TO ORTHO-DISUBSTITUTED (ETA-6-ARENE)CR(CO)3 COMPLEXES [J].

AUBE, J ;

HEPPERT, JA ;

MILLIGAN, ML ;

SMITH, MJ ;

ZENK, P .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (13) :3563-3570

[3] THE DIASTEREOSELECTIVE FUNCTIONALIZATION OF ARENE TRICARBONYLCHROMIUM COMPLEXES CONTAINING A BENZYLIC HETEROATOM SUBSTITUENT [J].

BLAGG, J ;

DAVIES, SG ;

GOODFELLOW, CL ;

SUTTON, KH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (08) :1805-1811

[4] ARENE-METAL COMPLEXES .12. REACTION OF (ETA-6-BENZENE)TRICARBONYLCHROMIUM WITH NORMAL-BUTYLLITHIUM [J].

CARD, RJ ;

TRAHANOVSKY, WS .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (13) :2555-2559

[5] ARENE-METAL COMPLEXES .13. REACTION OF SUBSTITUTED (BENZENE)TRICARBONYLCHROMIUM COMPLEXES WITH NORMAL-BUTYLLITHIUM [J].

CARD, RJ ;

TRAHANOVSKY, WS .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (13) :2560-2566

[6]

CHERNEGA AN, IN PRESS

[7]

CLOUGH JM, 1990, SYNLETT, P469

[8] TRICARBONYLCHROMIUM(0) PROMOTED STEREOSELECTIVE TRANSFORMATIONS OF EPHEDRINE AND PSEUDOEPHEDRINE DERIVATIVES [J].

COOTE, SJ ;

DAVIES, SG ;

GOODFELLOW, CL ;

SUTTON, KH ;

MIDDLEMISS, D ;

NAYLOR, A .

TETRAHEDRON-ASYMMETRY, 1990, 1 (11) :817-842

[9] ASYMMETRIC-SYNTHESIS OF R-ALPHA-METHYL-ORTHO-METHOXYBENZYL METHYL-ETHER VIA THE DIASTEREOSELECTIVE FUNCTIONALIZATION OF (+)-(ORTHO-METHOXYBENZYL METHYL-ETHER)CHROMIUM TRICARBONYL [J].

DAVIES, SG ;

GOODFELLOW, CL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) :C5-C8

[10] ASYMMETRIC-SYNTHESIS OF THE ENANTIOMERS OF THE DIARYLCARBINOL (1R)-1-(1-HYDROXYPHENYLMETHYL)-2-HYDROXYBENZENE AND (1S)-1-(1-HYDROXYPHENYLMETHYL)-2-HYDROXYBENZENE [J].

DAVIES, SG ;

HUME, WE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) :251-252

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