TACTICITY EFFECTS ON POLYMER BLEND MISCIBILITY

被引：48

作者：

BEAUCAGE, G

STEIN, RS

HASHIMOTO, T

HASEGAWA, H

机构：

[1] UNIV MASSACHUSETTS,DEPT POLYMER SCI & ENGN,AMHERST,MA 01003

[2] KYOTO UNIV,DEPT POLYMER CHEM,KYOTO 606,JAPAN

来源：

MACROMOLECULES | 1991年 / 24卷 / 11期

关键词：

D O I：

10.1021/ma00011a062

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility of amorphous, vinyl polymers depends upon the molecular weights and tacticities of the blend components. In this investigation blends of polystyrene (PS) and poly(vinyl methyl ether) (PVME) were studied. Three isotactic poly(vinyl methyl ether) (PVME) samples, synthesized in our laboratories, and one heterotactic PVME sample have been characterized by GPC, NMR, X-ray diffraction, and DSC. Atactic PS of three molecular weights were used. Cloud-point measurements were made with a light scattering apparatus. It was found that isotactic PVME is less miscible with atactic PS than heterotactic PVME.

引用

页码：3443 / 3448

页数：6

共 20 条

[1] BANK MI, 1969, POLYM PREP-ACS, V10, P622
[2] CHARACTERIZATION OF THE MOLECULAR-WEIGHT DISTRIBUTION OF HIGH-DENSITY POLYETHYLENE BY A NEW METHOD USING THE TURBIDITY AT A LOWER CRITICAL SOLUTION TEMPERATURE
BARBALATA, A
BOHOSSIAN, T
PROCHAZKA, K
DELMAS, G
[J]. MACROMOLECULES, 1988, 21 (11) : 3286 - 3295
[3] BASSI IW, 1960, ATTI ACCAD NAZ LINCE, V29, P193
[4] THERMODYNAMIC PROPERTIES OF POLYOLEFIN SOLUTIONS AT HIGH-TEMPERATURE .1. LOWER CRITICAL SOLUBILITY TEMPERATURES OF POLYETHYLENE, POLYPROPYLENE AND ETHYLENE-PROPYLENE CO-POLYMERS IN HYDROCARBON SOLVENTS
CHARLET, G
DELMAS, G
[J]. POLYMER, 1981, 22 (09) : 1181 - 1189
[5] OBSERVATION AND IDENTIFICATION OF TETRAD SEQUENCES IN DEUTERATED POLY(VINYL METHYL ETHER)
DOMBROSKI, JR
SARKO, A
SCHUERCH, C
[J]. MACROMOLECULES, 1971, 4 (01) : 93 - +
[6] TIME-RESOLVED LIGHT-SCATTERING-STUDIES ON KINETICS OF PHASE-SEPARATION AND PHASE DISSOLUTION OF POLYMER BLENDS .1. KINETICS OF PHASE-SEPARATION OF A BINARY MIXTURE OF POLYSTYRENE AND POLYVINYL METHYL-ETHER)
HASHIMOTO, T
KUMAKI, J
KAWAI, H
[J]. MACROMOLECULES, 1983, 16 (04) : 641 - 648
[7] Karasz F., 1968, MACROMOLECULES, V1, P537
[8] INFLUENCE OF THE TACTICITY OF POLY(METHYL METHACRYLATE) ON ITS MISCIBILITY WITH CHLORINATED POLYMERS
LEMIEUX, E
PRUDHOMME, RE
FORTE, R
JEROME, R
TEYSSIE, P
[J]. MACROMOLECULES, 1988, 21 (07) : 2148 - 2154
[9] LENZ RW, 1967, ORGANIC CHEM SYNTHET, P524
[10] NATTA G, 1963, CHIM IND-MILAN, V45, P229

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