MECHANISM OF REACTIONS ON MULTIMETALLIC CATALYSTS

被引：61

作者：

GUCZI, L

机构：

[1] Hungarian Acad of Sciences, Inst of, Isotopes, Budapest, Hung, Hungarian Acad of Sciences, Inst of Isotopes, Budapest, Hung

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1984年 / 25卷 / 1-3期

关键词：

ALUMINA - Applications - HYDROCARBONS - Chemical Reactions - METALS AND ALLOYS - Applications - SILICA - Applications;

D O I：

10.1016/0304-5102(84)80028-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A bimetallic system is frequently superior in its behavior to a monometallic catalyst. The following effects may be considered to rationalize the existing data: formation of bimetallics but segregation occurs; particle size effect, dispersion; matrix effect, e. g. one component grafted to the support; change in hydrogen coverage; metal-support interaction (MSI); suppression of ageing effects, such as coke formation. These effects are discussed here for a series of examples, e. g. Ru-Cu, Ru-Au, Ru-Pt, Ru-Fe, Pt-Au, Pt-Ir, Pt-Fe bimetallic systems, considering the influence of the factors mentioned for different hydrocarbon transformations as well as for hydrocarbon synthesis.

引用

页码：13 / 29

页数：17

共 99 条

[1] ADSORPTION AND TEMPERATURE-PROGRAMMED DESORPTION OF HYDROGEN WITH DISPERSED PLATINUM AND PLATINUM-GOLD CATALYSTS [J].

ANDERSON, JR ;

FOGER, K ;

BREAKSPERE, RJ .

JOURNAL OF CATALYSIS, 1979, 57 (03) :458-475

[2]

[Anonymous], 2021, J CATAL, V11, P1

[3] ELECTRONIC-PROPERTIES OF METAL-CLUSTERS [J].

BAETZOLD, RC .

SURFACE SCIENCE, 1981, 106 (1-3) :243-250

[4] PROPERTIES OF SMALL METAL PARTICLES [J].

BAETZOLD, RC ;

HAMILTON, JF .

PROGRESS IN SOLID STATE CHEMISTRY, 1983, 15 (01) :1-53

[5] BIMETALLIC RUTHENIUM-GOLD-ON-MAGNESIA CATALYSTS - CHEMICOPHYSICAL PROPERTIES AND CATALYTIC ACTIVITY [J].

BASSI, IW ;

GARBASSI, F ;

VLAIC, G ;

MARZI, A ;

TAUSZIK, GR ;

COCCO, G ;

GALVAGNO, S ;

PARRAVANO, G .

JOURNAL OF CATALYSIS, 1980, 64 (02) :405-416

[6] CATALYTIC DEHYDROGENATION OF PROPANE TO PROPENE OVER PLATINUM AND PLATINUM-GOLD ALLOYS [J].

BILOEN, P ;

DAUTZENBERG, FM ;

SACHTLER, WMH .

JOURNAL OF CATALYSIS, 1977, 50 (01) :77-86

[7] INTERACTION OF SMALL SILICA SUPPORTED PLATINUM-RUTHENIUM ALLOY PARTICLES WITH HYDROGEN AND OXYGEN [J].

BLANCHARD, G ;

CHARCOSSET, H ;

GUENIN, M ;

TOURNAYAN, L .

SURFACE SCIENCE, 1981, 106 (1-3) :509-515

[8] HYDROGEN TITRATION, SCANNING ELECTRON-MICROSCOPY, AND ASSOCIATED X-RAY-EMISSION STUDIES OF PT-RU-AL2O3 CATALYSTS [J].

BLANCHARD, G ;

CHARCOSSET, H ;

DEXPERT, H ;

FREUND, E ;

LECLERCQ, C ;

MARTINO, G .

JOURNAL OF CATALYSIS, 1981, 70 (01) :168-176

[9] KINETICS AND MECHANISM OF CARBON-MONOXIDE HYDROGENATION OVER SILICA-SUPPORTED RUTHENIUM-COPPER CATALYSTS [J].

BOND, GC ;

TURNHAM, BD .

JOURNAL OF CATALYSIS, 1976, 45 (02) :128-136

[10] MORPHOLOGY AND COMPOSITION OF PT-PD ALLOY CRYSTALLITES ON SIO2 IN REACTIVE ATMOSPHERES [J].

CHEN, M ;

SCHMIDT, LD .

JOURNAL OF CATALYSIS, 1979, 56 (02) :198-218

← 1 2 3 4 5 6 7 8 9 10 →