SYNTHESIS AND GAS-CHROMATOGRAPHIC SEPARATION OF THE 8 STEREOISOMERS OF DIPRIONOL AND THEIR ACETATES, COMPONENTS OF THE SEX-PHEROMONE OF PINE SAWFLIES

被引：71

作者：

HOGBERG, HE

HEDENSTROM, E

WASSGREN, AB

HJALMARSSON, M

BERGSTROM, G

LOFQVIST, J

NORIN, T

机构：

[1] LUND UNIV, DEPT ANIM ECOL, S-22362 LUND, SWEDEN

[2] GOTHENBURG UNIV, DEPT CHEM ECOL, S-40033 GOTHENBURG, SWEDEN

[3] ROYAL INST TECHNOL, DEPT ORGAN CHEM, S-10044 STOCKHOLM 70, SWEDEN

来源：

TETRAHEDRON | 1990年 / 46卷 / 08期

关键词：

D O I：

10.1016/S0040-4020(01)88392-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The present report describes syntheses of the eight possible stereoisomers of 3,7-dimediyl-2-pentadecanol 1, and the corresponding acetates. The latter are components of the sex pheromone of the Neodiprion, Diprion and Gilpinia genera (Diprionidae). Synthetic intermediates were prepared from either chiral starting materials or by asymmetric syntheses. The stereochemical compositions of the isomeric diprionols were determined by using capillary gas chromatography on tandem column systems, some with chiral phase coatings. © 1990.

引用

页码：3007 / 3018

页数：12

共 53 条

[1] TRANS-PERILLENAL - FURANOID MONOTERPENE FROM PINE SAW-FLY, NEODIPRION-SERTIFER (HYMENOPTERA, DIPRIONIDAE) [J].