STUDY OF DESORPTION ACTIVATION-ENERGY ON RH-CO SYSTEMS

被引:5
作者
NEHASIL, V
STARA, I
MATOLIN, V
机构
[1] Department of Electronics and Vacuum Physics, Charles University, Praha 8, 180 00
关键词
D O I
10.1007/BF01595286
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The adsorption of CO on an Rh foil and small Rh particles supported by Al2O3 polycrystalline surfaces was studied using the temperature programmed desorption (TPD). The supported Rh particles were prepared by evaporation, using the principles of electron bombardment. The activation energy of desorption was calculated. The results show the dependence on the CO exposure of the sample as well as the size effect. The desorption and the recombination peaks were measured. The dissociation of CO and the influence of C atoms on the surface are discussed.
引用
收藏
页码:957 / 961
页数:5
相关论文
共 4 条
[1]  
[Anonymous], 1962, VACUUM
[2]  
BELTON DN, 1908, SURF SCII, V202, P238
[3]   ADSORPTION AND DISSOCIATION OF CO ON RH(210) [J].
REBHOLZ, M ;
PRINS, R ;
KRUSE, N .
SURFACE SCIENCE, 1991, 259 (03) :L797-L803
[4]   MODERN CONCEPTS IN SURFACE SCIENCE AND HETEROGENEOUS CATALYSIS [J].
SOMORJAI, GA .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (03) :1013-1023