PICOSECOND TIME RESOLUTION OF POLARIZED FLUORESCENCE FROM NORMAL-ALKANE VANDERWAALS COMPLEXES OF JET-COOLED 2,5-DIPHENYLFURAN - IDENTIFICATION OF DIFFERENT STRUCTURAL ISOMERS

被引：12

作者：

KAZISKA, AJ

SHCHUKA, MI

TOPP, MR

机构：

[1] Department of Chemistry, University of Pennsylvania, Philadelphia

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 183卷 / 06期

关键词：

D O I：

10.1016/0009-2614(91)80174-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experiments monitoring temporal recurrences of the fluorescence polarization anisotropy in a supersonic jet have been used to monitor the inertial properties of n-alkane complexes of the polycyclic aromatic hydrocarbon 2,5-diphenylfuran (PPF). Semi-empirical predictions for the structure of the octane complex have been verified and two different conformational isomers of PPF/nonane have been resolved and identified.

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页码：552 / 557

页数：6

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