MACROCYCLIC DITHIOMALEONITRILE DERIVATIVES CONTAINING SULFUR AND NITROGEN HETEROATOMS

被引：23

作者：

LANGE, SJ

SIBERT, JW

STERN, CL

BARRETT, AGM

HOFFMAN, BM

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

TETRAHEDRON | 1995年 / 51卷 / 30期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4020(95)00439-F

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general synthetic method for incorporation of the dithiomaleonitrile unit into macrocycles containing sulfur, oxygen, and nitrogen heteroatoms is presented along with the single-crystal X-ray structures of the thiacrowns. In addition to being new ligands, these macrocycles are direct precursors to peripherally crown functionalized porphyrazines capable of coordinating multiple metal ions.

引用

页码：8175 / 8188

页数：14

共 36 条

[1] EFFECT OF LIGAND CONSTRAINTS UPON THE STABILITIES AND POTENTIALS OF MACROCYCLIC POLYTHIAETHER COMPLEXES - COPPER(II) AND COPPER(I) COMPLEXES WITH CYCLOHEXYL AND PHENYL DERIVATIVES OF [14]ANES(4) IN WATER, 80-PERCENT METHANOL, AND ACETONITRILE [J].