PHASE-TRANSFER-CATALYZED P-C BOND-CLEAVAGE IN PLATINUM BIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES UNDER EXCEEDINGLY MILD CONDITIONS

被引：28

作者：

LIN, IJB

LAI, JS

LIU, CW

机构：

[1] Department of Chemistry, Fu Jen Catholic University Hsinchuang

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 02期

关键词：

D O I：

10.1021/om00116a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Pt(dppm)Cl2] (dppm = Ph2PCH2PPh2) with [S(O)Me3]Cl under basic phasetransfer- catalyzed conditions gave the complex {Pt- (PPh2Me)[PPh2(OH)] [(CH2)2S(O)Me]}Cl, which contains a bidentate sulfur ylide and two monodentate phosphine ligands. The latter was produced by the facile base hydrolysis of the dppm ligand, a reaction that is general for other Pt-dppm complexes. © 1990, American Chemical Society. All rights reserved.

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页码：530 / 531

页数：2

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