SYNTHESIS AND REACTIVITY OF DIHYDROXORUTHENIUM(IV) COMPLEX OF TETRAMESITYLPORPHYRIN - AEROBIC EPOXIDATION OF NORBORNENE BY RUTHENIUM PORPHYRINS

被引：32

作者：

LEUNG, WH

CHE, CM

YEUNG, CH

POON, CK

机构：

[1] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG

[2] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

POLYHEDRON | 1993年 / 12卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83049-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Ru(TMP)(CO) with m-CPBA in CH2Cl2/EtOH afforded Ru (TMP)(OH)2, isolated as air-stable violet crystals. Ru(TMP)(OH)2 is paramagnetic (mu(eff) ca 2.7 B.M.) and displays broad H-1 NMR signals with paramagnetic isotropic shifts. The IR spectrum shows a band at 760 cm-1 assignable to the Ru-O stretch. Ru(TMP)(OH)2 is capable of catalysing aerobic epoxidation of alkenes under mild conditions.

引用

页码：2331 / 2334

页数：4

共 19 条

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