REACTIONS OF HIGHLY ELECTROPHILIC POLYFLUOROCARBONYL COMPOUNDS WITH PRIMARY ARYLAMINES

被引：7

作者：

CHKANIKOV, ND

SVIRIDOV, VD

ZELENIN, AE

GALAKHOV, MV

KOLOMIETS, AF

FOKIN, AV

机构：

[1] A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 02期

关键词：

D O I：

10.1007/BF00960662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C-Hydroxyalkylation of primary arylamines by highly electrophilic polyfluorocarbonyl compounds results from the direct reaction of the initial reagents and is competitively inhibited by equilibrium N-hydroxyalkylation. The presence of steric hindrances to the formation of N-hydroxyalkylation products and an increase in the ring C-nucleophilicity facilitate the C-hydroxyalkylation reaction. © 1990 Plenum Publishing Corporation.

引用

页码：323 / 328

页数：6

共 10 条

[1]

CHKANIKOV ND, 1986, IZV AKAD NAUK SSSR K, P2290

[2] PERHALO KETONES .6. AROMATIC AMINO DERIVATIVES OF PERHALOACETONES [J].

GILBERT, EE ;

JONES, ES ;

SIBILIA, JP .

JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (04) :1001-&

[3]

KNUNYANTS IL, 1960, ZH VSES KHIM OVA+, V5, P114

[4]

KNUNYANTS IL, 1962, IAN SSSR KH, P684

[5]

SALOUTIN VI, 1982, 4TH ALL UN C CHEM FL, P79

[6]

Zelenin A. E., 1986, IAN SSSR KH, P2074

[7]

ZELENIN AE, 1986, IAN SSSR KH, P2080

[8]

ZELENIN AE, 1988, IAN SSSR KH, P121

[9]

ZELENIN AE, 1987, IAN SSSR KH, P231

[10]

ZELENIN AE, 1985, IAN SSSR KH, P955

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