Small basalt to dacite volcanic centers are distributed sparsely over the Bolivian Altiplano, behind the Andean volcanic front. Most are Pliocene to Recent in age, and are characterized by textural and mineralogical disequilibrium with abundant xenoliths and xenocrysts. True phenocrysts are rare in the more mafic samples. Compared with Recent volcanic rocks from Andean stratovolcanoes, the Bolivian centers overlap in major element trends. Incompatible element contents tend to be higher, particularly in the eastern Altiplano. The ranges of isotopic compositions reflect ubiquitous crustal contamination. Pb isotope compositions are dominated by Pb from isotopically heterogeneous basement, resulting in a wide scatter of data lying between inferred crustal compositions and showing little overlap with possible mantle sources in the region. Rocks sampled from the Bolivian Altiplano were probably derived from asthenospheric mantle and subjected to extensive open system differentiation during ascent through the 70 km thick crust of the region. Major element trends are largely controlled by the fractionating phase assemblage (olivine, clinopyroxene and amphibole). Trace element and isotope systematics, however, defy realistic attempts at modeling due to the geographic scatter of samples, the uniformity of compositions at a given center, and the heterogeneity of the contaminant. Nevertheless, there are first order systematic trace element variations that appear to relate to the geometry of the subduction zone. In particular, LILE/HFSE (exemplified by Ba/Nb), and Zr/Nb ratios decrease from the are front eastward into the Altiplano. These variations are not easily reconciled with control by crustal contamination alone. A model is proposed in which the asthenospheric source is fluxed by high Ba/Nb slab-derived fluid to induce melting. Beneath the are, high fluid flux increases the Ba/Nb ratio of the asthenosphere and leads to high degrees of partial melting (high Zr/Nb). To the east, lower or no fluid flux leads to low Ba/Nb and low degrees of partial melting (low Zr/Nb). Melting in the back are region of the Altiplano may be facilitated by lithospheric delamination that leads to decompression melting of counter-flowing asthenosphere. There is no unequivocal evidence that requires a significant role for the lithospheric mantle.
