CHLORINE INPUT AND OUTPUT IN COMBUSTION OF MUNICIPAL SOLID-WASTE IN A LAB-SCALE MINI-REACTOR SYSTEM

被引：4

作者：

KANTERS, J

LOUW, R

机构：

[1] Center of Chemistry and the Environment, Leiden Institute of Chemistry, Gorlaeus Laboratories, 2300 RA Leiden

来源：

CHEMOSPHERE | 1994年 / 29卷 / 9-11期

关键词：

MUNICIPAL SOLID WASTE; COMBUSTION; CHLOROPHENOLS; DIOXINS;

D O I：

10.1016/0045-6535(94)90357-3

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Regular and modified samples of real MSW have been combusted in a mini-model reactor mimicking practical MSW incineration. Emitted Chloro-Phenols (CP) have been taken as an indicator for 'dioxin'-formation. Using humid air as the carrier gas, an even 8-fold increase of the PVC load hardly leads to ''extra'' CPs which is ascribed to the chlorine load due to inorganic chlorine. Also, when replacing the compostables and the other important chlorine carrying fractions - including PVC - by cellulose and NaCl, the level of CP emission does not change. When using humid air enriched with HCl, the CP emission lever is higher. When the amounts of PVC and compostables are reduced the CP emission is lowered.

引用

页码：1919 / 1925

页数：7

共 20 条

[1] DIOXIN EMISSIONS FROM WASTE INCINERATORS [J].

BARTON, RG ;

CLARK, WD ;

LANIER, WS ;

SEEKER, WR .

CHEMOSPHERE, 1990, 20 (10-12) :1825-1832

[2]

BORN JP, 1992, THESIS LEIDEN U

[3] COMBUSTION OF POLYVINYLCHLORIDE - AN IMPORTANT SOURCE FOR THE FORMATION OF PCDD/PCDF [J].

CHRISTMANN, W ;

KASISKE, D ;

KLOPPEL, KD ;

PARTSCHT, H ;

ROTARD, W .

CHEMOSPHERE, 1989, 19 (1-6) :387-392

[4] SURFACE-CATALYZED FORMATION OF CHLORINATED DIBENZODIOXINS AND DIBENZOFURANS DURING INCINERATION [J].

DICKSON, LC ;

LENOIR, D ;

HUTZINGER, O .

CHEMOSPHERE, 1989, 19 (1-6) :277-282

[5]

DROYZD J, 1981, J CHROMATOGR, V19, P84

[6]

DUWEL U, 1991, UNTERSUCHUNG URSACHE

[7]

GUILIANO M, 1989, CHEMOSPHERE, V19, P407

[8] CHARACTERISTICS OF MUNICIPAL SOLID-WASTE INCINERATOR FLY-ASH PROMOTING THE FORMATION OF POLYCHLORINATED DIOXINS [J].

HINTON, WS ;

LANE, AM .

CHEMOSPHERE, 1991, 22 (5-6) :473-483

[9]

JANSSENS H, 1988, 738473002 SPEC REP S, P19

[10]

KANTERS J, 1992, CCESRS9206 SPEC REP

← 1 2 →