SYSTEM BI2-X-YPBXBYRU2O7-Z (B = MG, CA, SR, CO, NI, CU, ZN, CD)

被引：4

作者：

BECK, E

KEMMLERSACK, S

机构：

[1] Univ Tuebingen, Inst fuer, Anorganische Chemie, Tuebingen, West, Ger, Univ Tuebingen, Inst fuer Anorganische Chemie, Tuebingen, West Ger

来源：

JOURNAL OF THE LESS-COMMON METALS | 1985年 / 113卷 / 01期

关键词：

LEAD COMPOUNDS - RUTHENIUM COMPOUNDS;

D O I：

10.1016/0022-5088(85)90148-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New pyrochlore phases can be obtained in the systems Bi//2// minus //x// minus //yPb//xB//y-Ru//2O//7// minus //z by partial substitution of B (B EQUVLNT Mg, Ca, Sr, Co, Ni, Cu, Zn, Cd) for Bi**3** plus . The phase boundary shifts to higher y values with increasing B radii (except for B EQUVLNT Sr). The high electric conductivity is preserved for all the pyrochlore phases.

引用

页码：65 / 74

页数：10

共 14 条

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