THE MACROLIDIC GLYCOLIPID CALONYCTIN-A, A PLANT-GROWTH REGULATOR - SYNTHESIS, STRUCTURAL ASSIGNMENT, AND CONFORMATIONAL-ANALYSIS IN MICELLAR SOLUTION

被引：34

作者：

JIANG, ZH ^{[1
]}

GEYER, A ^{[1
]}

SCHMIDT, RR ^{[1
]}

机构：

[1] UNIV KONSTANZ,FAK CHEM,D-78434 CONSTANCE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

CALONYCTIN A; GLYCOLIPIDS; GLYCOSIDE SYNTHESES; MACROLIDES; MOLECULAR DYNAMICS SIMULATION;

D O I：

10.1002/anie.199525201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tetrasaccharide, nilic acid, and jalapinolic acid served as building blocks in the total synthesis of calonyctin A (1) (n = 1, 2). The conformation of this amphiphilic glycolipid was studied in micellar solution by NMR spectroscopy and molecuar dynamics simulation. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2520 / 2524

页数：5

共 27 条

[1] PREDICTION OF ANTI AND GAUCHE VICINAL PROTON-PROTON COUPLING-CONSTANTS IN CARBOHYDRATES - A SIMPLE ADDITIVITY RULE FOR PYRANOSE RINGS [J].