SIMPLE STEREOSPECIFIC SYNTHESES OF (E)-1-CHLORO(OR BROMO)ALK-1-ENES FROM ALK-1-YNES VIA HYDROBORATION

被引：16

作者：

MASUDA, Y

HOSHI, M

ARASE, A

机构：

[1] Department of Industrial Chemistry, Kitami Institute of Technology

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 21期

关键词：

D O I：

10.1039/p19920002725

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereochemically pure (E)-1-chloro(or bromo)alk-1-enes were obtained in sufficiently good yields from alk-1 -ynes via hydroboration with dialkylborane followed by reactions with facile reagents; corresponding copper(II) halides, in the presence of a small amount of water, in polar aprotic solvents.

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页码：2725 / 2726

页数：2

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