A DIPHENYLFORMAMIDINATE-BRIDGED TERPYRIDINEPLATINUM(II) DIMER

被引：22

作者：

BAILEY, JA ^{[1
]}

MISKOWSKI, VM ^{[1
]}

GRAY, HB ^{[1
]}

机构：

[1] CALTECH,BECKMAN INST,PASADENA,CA 91125

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192010229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound mu-N,N'-diphenylformamidinato-bis [2,2',2''-terpyridineplatinum(II)] perchlorate monohydrate (1) is formed by reaction of diphenyl-formamidine and [Pt(tpy)Cl]Cl (tpy = terpyridine) in the presence of excess base. The two platinum centers are bridged by a single diphenylformamidinato ligand with the remaining coordination geometry completed by the terpyridine group. The platinum-platinum separation is 3.049 (1) angstrom.

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页码：793 / 796

页数：4

相关论文

共 11 条

[1] A MU-PYRAZOLYL TERPYRIDINEPLATINUM(II) DIMER [J].

BAILEY, JA ;

GRAY, HB .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1420-1422

[2]

Cromer D T, 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]

[3]

CROMER DT, 1974, INT TABLES XRAY CRYS, V4, P149

[4] SYNTHESIS AND STRUCTURE OF A BIS[TERPYRIDINEPLATINUM(II)] COMPLEX AND ITS EVALUATION AS A METALLOINTERCALATOR [J].

DEWAN, JC ;

LIPPARD, SJ ;

BAUER, WR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :858-860

[5]

DUCHAMP DJ, 1964, AM CRYSTALLOGR ASS M, P29

[6] METALLOINTERCALATION REAGENTS - SYNTHESIS, CHARACTERIZATION, AND STRUCTURAL-PROPERTIES OF THIOLATO(2,2',2''-TERPYRIDINE)PLATINUM(II) COMPLEXES [J].

JENNETTE, KW ;

GILL, JT ;

SADOWNICK, JA ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (20) :6159-6168

[7]

JOHNSON CK, 1976, ORNL3794 REP

[8]

LARSON AC, 1967, ACTA CRYSTALLOGR, V23, P644

[9] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF THE RH2(4+) COMPLEX RH2(N,N'-DI-PARA-TOLYLFORMAMIDINATE ANION)4 [J].

PIRAINO, P ;

BRUNO, G ;

LOSCHIAVO, S ;

LASCHI, F ;

ZANELLO, P .

INORGANIC CHEMISTRY, 1987, 26 (14) :2205-2211

[10] TERMINAL AND NEW BRIDGING COORDINATION OF METHYLGUANIDINE, ARGININE, AND CANAVANINE TO PLATINUM(II) - THE 1ST CRYSTALLOGRAPHIC STUDY OF BONDING BETWEEN A TRANSITION-METAL AND A GUANIDINE LIGAND [J].

RATILLA, EMA ;

SCOTT, BK ;

MOXNESS, MS ;

KOSTIC, NM .

INORGANIC CHEMISTRY, 1990, 29 (05) :918-926