A DIPHENYLFORMAMIDINATE-BRIDGED TERPYRIDINEPLATINUM(II) DIMER

被引：22

作者：

BAILEY, JA ^{[1
]}

MISKOWSKI, VM ^{[1
]}

GRAY, HB ^{[1
]}

机构：

[1] CALTECH,BECKMAN INST,PASADENA,CA 91125

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192010229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound mu-N,N'-diphenylformamidinato-bis [2,2',2''-terpyridineplatinum(II)] perchlorate monohydrate (1) is formed by reaction of diphenyl-formamidine and [Pt(tpy)Cl]Cl (tpy = terpyridine) in the presence of excess base. The two platinum centers are bridged by a single diphenylformamidinato ligand with the remaining coordination geometry completed by the terpyridine group. The platinum-platinum separation is 3.049 (1) angstrom.

引用

页码：793 / 796

页数：4