COMPARISON OF THE ELECTROPHILICITIES OF CATIONIC METAL PI-COMPLEXES AND OF ORDINARY CARBENIUM IONS

被引：23

作者：

MAYR, H

MULLER, KH

RAU, D

机构：

[1] Institut Für Organische Chemie, Technischen Hochschule Darmstadt, D-64287

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrophilicity of tricarbonyl(cycloalkadienylium)iron complexes like 1 was determined by measuring the rates of their reactions with nucleophiles like 2 to give the neutral complexes 3 [Eq. (a)]. This enables the integration of the electrophilicity scale of organometallic cations with that of carbenium ions. Counterion BF 4−; R is, for example, Ph. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1630 / 1632

页数：3

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