OBSERVATIONS ON SELECTIVITY REVERSAL DURING CHIRAL AUXILIARY-DIRECTED ASYMMETRIC NUCLEOPHILE ADDITIONS TO ARENE-MANGANESE TRICARBONYL COMPLEXES

被引：18

作者：

PEARSON, AJ ^{[1
]}

MILLETTI, MC ^{[1
]}

ZHU, PY ^{[1
]}

机构：

[1] EASTERN MICHIGAN UNIV,DEPT CHEM,YPSILANTI,MI 48197

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study of hydride nucleophile reactions with eta(6)-(2R, 5R)-dimethylpyrrolidinylbenzene-manganes tricarbonyl hexafluorophosphate 1 reveals an unexpected reversal of selectivity during addition of hydride to the diastereotopic meta carbons, which is explained on the basis of changes in transition state location as the reactivity of the nucleophile is varied.

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页码：853 / 854

页数：2

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