CONDENSATION OF FORMALDEHYDE WITH CHELATED GLYCINE AND ETHYLENEDIAMINE - NEW MACROCYCLE SYNTHESIS - X-RAY STRUCTURES OF [ALPHA-HYDROXYMETHYLSERINE-BIS(ETHYLENEDIAMINE)COBALT(III)]2+ AND [ALPHA-HYDROXYMETHYLSERINE-1,4,8,11-TETRA-AZA-6,13-DIOXACYCLOTETRADECANECOBALT(III)]2+ IONS

被引：27

作者：

GEUE, RJ

SNOW, MR

SPRINGBORG, J

HERLT, AJ

SARGESON, AM

TAYLOR, D

机构：

[1] ROY VET & AGR UNIV, DEPT CHEM, DK-1871 COPENHAGEN, DENMARK

[2] UNIV ADELAIDE, DEPT PHYS & INORG CHEM, ADELAIDE 5001, S AUSTRALIA, AUSTRALIA

[3] AUSTRALIAN NATL UNIV, SCH CHEM RES, CANBERRA 2600, ACT, AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1976年 / 08期

关键词：

D O I：

10.1039/c39760000285

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Condensation of formaldehyde with glycinatobis-(ethylenediamine)cobalt(III) ion yields in turn [.alpha.-hydroxymethylserinebis(ethylenediamine)cobalt(III)]2+ and the macrocycle [.alpha.-hydroxymethylserine-1,4,8,11-tetraaza-6,13-dioxacyclotetradecanecobalt(III)]2+, the structures of which have been established by X-ray structural analysis.

引用

页码：285 / 287

页数：3

共 4 条

[1] A SYNTHESIS AND RESOLUTION OF DL-SERINE [J].