1,3-ASYMMETRIC INDUCTION - HIGHLY ENANTIOSELECTIVE SYNTHESIS OF ALPHA-AMINO-ACIDS VIA 2,5-TRANS DISUBSTITUTED IMIDAZOLIDIN-4-ONES

被引：17

作者：

AMOROSO, R ^{[1
]}

CARDILLO, G ^{[1
]}

TOMASINI, C ^{[1
]}

机构：

[1] UNIV BOLOGNA,CTR STUDIO FIS MACROMOLEC,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 17期

关键词：

D O I：

10.1016/0040-4039(91)85016-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,5-Trans imidazolidin-4-ones have been obtained from mercury promoted cyclisation of unsaturated amidals containing a stereogenic centre. A new enantioselective synthesis of alpha-amino acids has been devised.

引用

页码：1971 / 1974

页数：4

共 12 条

[1] AMOROSO R, 1990, TETRAHEDRON LETT, V44, P6413
[2] STUDIES ON AMINO-ACIDS AND PEPTIDES .4. 1,2,4-TRIAZINES FROM THIOACYLATED AMINO-ACID ESTERS
ANDERSEN, TP
GHATTAS, ABAG
LAWESSON, SO
[J]. TETRAHEDRON, 1983, 39 (20) : 3419 - 3427
[3] BARTLETT P, 1984, ASYMMETRIC SYNTHESIS, V3
[4] SYNTHESIS OF N-SUBSTITUTED AZIRIDINE-2-CARBOXYLATES
BERNSTEIN, Z
BENISHAI, D
[J]. TETRAHEDRON, 1977, 33 (08) : 881 - 883
[5] SYNTHESIS OF AMINOALCOHOLS VIA PERIHYDRO-1,3-OXAZIN-2-ONES AND ABSOLUTE-CONFIGURATION ASSIGNMENT THROUGH MM2 CALCULATIONS
BONGINI, A
CARDILLO, G
ORENA, M
PORZI, G
SANDRI, S
[J]. CHEMISTRY LETTERS, 1988, (01) : 87 - 90
[6] STEREOCONTROLLED CYCLOFUNCTIONALIZATIONS OF DOUBLE-BONDS THROUGH HETEROCYCLIC INTERMEDIATES
CARDILLO, G
ORENA, M
[J]. TETRAHEDRON, 1990, 46 (10) : 3321 - 3408
[7] SEQUENTIAL CHIRALITY TRANSFER IN INTRAMOLECULAR AMIDOMERCURATION REACTIONS
HARDING, KE
HOLLINGSWORTH, DR
REIBENSPIES, J
[J]. TETRAHEDRON LETTERS, 1989, 30 (36) : 4775 - 4778
[8] STEREOSELECTIVITY IN INTRAMOLECULAR AMIDOMERCURATION - KINETIC VS THERMODYNAMIC CONTROL
HARDING, KE
MARMAN, TH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (15) : 2838 - 2840
[9] APPLICATIONS OF INTRAMOLECULAR AMIDOMERCURATION .2. SYNTHESIS OF "TRANS-5-HYDROXY-2-PROPYLPIPERIDINE, (+/-)-PSEUDOCONHYDRINE
HARDING, KE
BURKS, SR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (01) : 40 - 44
[10] STEREOCONTROLLED SYNTHESIS OF CIS-2,5-DISUBSTITUTED TETRAHYDROFURANS AND CIS-LINALYL AND TRANS-LINALYL OXIDES
RYCHNOVSKY, SD
BARTLETT, PA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (13) : 3963 - 3964

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