INFLUENCE OF CO LIGANDS ON LITHIUM COORDINATION OF PHOSPHINOMETHANIDES AND MOLECULAR-STRUCTURE OF ((THF)LI[C(SIME3)2(PME2)])2

被引：17

作者：

KARSCH, HH

ZELLNER, K

GAMPER, S

MULLER, G

机构：

[1] Anorganisch-chemisches Institut der Technischen Universität München, W-8046 Garching

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)86107-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first lithium monophosphinomethanide complex with a monodentate co-ligand, {(THF)Li[C(SiMe3)2(PMe2)]}2 is obtained from the solvate-free complex and tetrahydrofuran (THF), and shown by X-ray crystallography to consist of a dinuclear, six-membered ring in a chair conformation with lithium atoms of coordination number three.

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页码：C39 / C44

页数：6

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