STRUCTURE DETERMINATION OF A COPPER-HISTAMINE CROCONATE COMPLEX [CU(C5O5)(C5H9N3)(OH2)].H2O

被引：24

作者：

CASTAN, P ^{[1
]}

DEGUENON, D ^{[1
]}

DAHAN, F ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270191007667

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aquacroconatohistaminecopper(II) monohydrate, C10H11CuN3O6.H2O, M(r) = 350.8, monoclinic, P2(1)/n, a = 7.418 (1), b = 17.070 (2), c = 10.851 (1) angstrom, beta = 108.48 (1)-degrees, V = 1303.2 (6) angstrom 3, Z = 4, D(x) = 1.788 Mg m-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 1.72 mm-1, F(000) = 716, T = 293 K, full-matrix least-squares refinement based on 1751 reflections led to R and wR values of 0.031 and 0.032 respectively. The metal is pentacoordinated. The coordination is ensured by one croconate molecule and one histamine molecule both acting as chelating ligands, and one water molecule.

引用

页码：2656 / 2658

页数：3

共 14 条

[1]

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[2]

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[3]

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